

Sometimes animals escape their enclosures and mis-feed themselves. The couple times I’ve witnessed this were the result of cows helping themselves to a field of alfalfa. Alfalfa is good as a component of a silage mix but is too rich to be consumed fresh on its own. But cows love alfalfa and are good at finding weaknesses in fencing.
The problem isn’t methane production, it’s excessive soluble proteins producing a thick foam that prevents the methane from being expelled through the esophagus. Any feed produces large amounts of gas in grazing animals. What changes is the animals ability to safely vent the gas.
https://biologyinsights.com/why-does-alfalfa-cause-bloat-in-cattle/